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Preheat the oven to 350ºF. Generously grease a 12 cup muffin tin with nonstick spray; set aside.
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Heat avocado oil in a large skillet over medium heat. Add onion and pepperand cook, stirring, until softened, about 5-6 minutes.
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Add broccoli and cook until softened, about 5 minutes more.
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Season vegetables with salt and pepper to taste. Remove from heat and set aside to cool.
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Add eggs, cottage cheese, tapioca starch and 1/2 teaspoon of salt to a blender. Blend until completely smooth.
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Evenly distribute the vegetable mixture in the prepared muffin pan.
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Pour the egg mixture evenly over the vegetables (the muffin cups should be about ¾ full) and give the contents of each cup a gentle stir.
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Bake for about 15-20 minutes, until the centers are just set (a small jiggle in the center is fine).
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Let cool for about 10 minutes, then run a butter knife around the edges if needed to help loosen. Transfer to a wire rack to cool. Enjoy immediately or store in a covered container in the refrigerator for 4-5 days.